- Title Pages
- Dedication
- Preface
- Acknowledgements
- Chapter 1 Structural principles in the classification of binary adducts
- Chapter 2 Historical outline
- PART II Moieties within molecules
- Chapter 3 The enclosure species – crown ethers, cryptands and related molecules – as hosts
- Chapter 4 Cyclodextrins, and some analogs, as hosts
- Chapter 5 Crystal chemistry of some DNA oligonucleotides and their complexes
- Part III Host-guest inclusion complexes
- Chapter 6 Tunnel inclusion complexes formed by hosts of lesser versatility
- Chapter 7 Clathrate inclusion complexes formed by hosts of lesser versatility
- Chapter 8 Inclusion complexes formed by versatile hosts
- Chapter 9 Intercalation complexes
- Part IV Packing complexes
- Chapter 10 Packing complexes
- Part V Molecular compounds with localized interactions
- Chapter 11 Donor–acceptor molecular compounds (essentially localized interactions)
- Chapter 12 Hydrogen bonded molecular complexes and compounds
- Part VI Molecular compounds with delocalized interactions
- Chapter 13 Charge transfer molecular compounds with delocalized π-π* interaction - introduction and general survey
- Chapter 14 Layered molecules with intra-molecular donor–acceptor interactions
- Chapter 15 Crystal chemistry of mixed-stack π–π* molecular compounds
- Chapter 16 Crystal (structural) physics of mixed stack π–π*molecular compounds
- Chapter 17 Segregated stack π-molecular complexes
- Appendix 1 Thermodynamic measurements on binary adducts
- [UNTITLED]
- Book Index
Structural principles in the classification of binary adducts
Structural principles in the classification of binary adducts
- Chapter:
- (p.3) Chapter 1 Structural principles in the classification of binary adducts
- Source:
- Crystalline Molecular Complexes and Compounds
- Author(s):
Frank H. Herbstein
- Publisher:
- Oxford University Press
When the properties of the individual components are largely conserved in the primary or intermediate crystalline phases of a two-component (A and B) system, then these phases are called ‘binary adducts’, which is a more formal name for what are usually called ‘molecular compounds and complexes’. The various types of binary adduct are classified in terms of those interactions between the components which determine the component arrangement in the crystal. Thus, A...A interactions dominate in inclusion complexes; A...A and B...B interactions are equally important in segregated-stack charge transfer complexes, all interactions are of roughly equal importance in packing complexes; and A...B interactions dominate in molecular compounds. This classification is compared to other complementary schemes.
Keywords: classification, binary adducts, molecular complexes and compounds
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- Title Pages
- Dedication
- Preface
- Acknowledgements
- Chapter 1 Structural principles in the classification of binary adducts
- Chapter 2 Historical outline
- PART II Moieties within molecules
- Chapter 3 The enclosure species – crown ethers, cryptands and related molecules – as hosts
- Chapter 4 Cyclodextrins, and some analogs, as hosts
- Chapter 5 Crystal chemistry of some DNA oligonucleotides and their complexes
- Part III Host-guest inclusion complexes
- Chapter 6 Tunnel inclusion complexes formed by hosts of lesser versatility
- Chapter 7 Clathrate inclusion complexes formed by hosts of lesser versatility
- Chapter 8 Inclusion complexes formed by versatile hosts
- Chapter 9 Intercalation complexes
- Part IV Packing complexes
- Chapter 10 Packing complexes
- Part V Molecular compounds with localized interactions
- Chapter 11 Donor–acceptor molecular compounds (essentially localized interactions)
- Chapter 12 Hydrogen bonded molecular complexes and compounds
- Part VI Molecular compounds with delocalized interactions
- Chapter 13 Charge transfer molecular compounds with delocalized π-π* interaction - introduction and general survey
- Chapter 14 Layered molecules with intra-molecular donor–acceptor interactions
- Chapter 15 Crystal chemistry of mixed-stack π–π* molecular compounds
- Chapter 16 Crystal (structural) physics of mixed stack π–π*molecular compounds
- Chapter 17 Segregated stack π-molecular complexes
- Appendix 1 Thermodynamic measurements on binary adducts
- [UNTITLED]
- Book Index