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Atomic and Laser Spectroscopy$
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Alan Corney

Print publication date: 2006

Print ISBN-13: 9780199211456

Published to Oxford Scholarship Online: September 2007

DOI: 10.1093/acprof:oso/9780199211456.001.0001

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The spontaneous emission of radiation

The spontaneous emission of radiation

(p.93) 4 The spontaneous emission of radiation
Atomic and Laser Spectroscopy

Alan Corney

Oxford University Press

Starting from a classical model of the atom, the classical rate at which energy is radiated is obtained and then converted into a quantum-mechanical transition rate. The calculation of the radiative lifetime of an excited atom is derived and expressions given for oscillator-strengths of spectral lines. Applications to hydrogenic systems and more complex atoms are also described.

Keywords:   spontaneous emission, radiative lifetime, oscillator strengths, hydrogenic systems

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