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Structural Crystallography of Inorganic Oxysalts$
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Sergey V. Krivovichev

Print publication date: 2009

Print ISBN-13: 9780199213207

Published to Oxford Scholarship Online: May 2009

DOI: 10.1093/acprof:oso/9780199213207.001.1

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Basic concepts

Basic concepts

(p.1) 1 Basic concepts
Structural Crystallography of Inorganic Oxysalts

Sergry V. Krivovichev

Oxford University Press

This chapter introduces basic concepts in structural chemistry relevant to the description and interpretation of structures of inorganic oxysalts. It starts from the structural classification of these materials using bond-valence theory and theory of mixed anionic radicals developed by the Moscow school of crystal chemistry. Typical bond lengths in inorganic oxysalts are tabulated and their behaviour is discussed. Some important parameters of hydrogen bonding are considered.

Keywords:   structural classification, bond-valence theory, bond lengths, coordination polyhedra, hydrogen bonding

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