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Structural Crystallography of Inorganic Oxysalts$
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Sergey V. Krivovichev

Print publication date: 2009

Print ISBN-13: 9780199213207

Published to Oxford Scholarship Online: May 2009

DOI: 10.1093/acprof:oso/9780199213207.001.1

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Topology of framework structures in inorganic oxysalts

Topology of framework structures in inorganic oxysalts

(p.94) 3 Topology of framework structures in inorganic oxysalts
Structural Crystallography of Inorganic Oxysalts

Sergry V. Krivovichev

Oxford University Press

This chapter deals with framework structures that represent one of the most complex units in inorganic oxysalts. The frameworks are considered from different viewpoints. First, several examples of structures based upon fundamental building units are considered and it is shown that many of them are organized on the basis of regular nets. However, most of the frameworks in oxysalts are much more complex and require detailed and sometimes non-trivial approaches for their interpretation. The frameworks are considered based upon polyhedral units, chains, or layers. Special attention is paid to the investigation of internal topologies of framework channels that are described by means of tubular units.

Keywords:   frameworks, fundamental building blocks, polyhedral units, nets, tubular units, chirality

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