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Structural Crystallography of Inorganic Oxysalts$
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Sergey V. Krivovichev

Print publication date: 2009

Print ISBN-13: 9780199213207

Published to Oxford Scholarship Online: May 2009

DOI: 10.1093/acprof:oso/9780199213207.001.1

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Dimensional reduction in inorganic oxysalts

Dimensional reduction in inorganic oxysalts

(p.215) 6 Dimensional reduction in inorganic oxysalts
Structural Crystallography of Inorganic Oxysalts

Sergry V. Krivovichev

Oxford University Press

This chapter analyses ‘structure-composition’ correlations in inorganic oxysalts by means of dimensional reduction. It is shown that the dimensionality of structural units in inorganic oxysalts is controlled by the incorporation of ionic component (e.g., alkali metal salt or oxide) into parent structure. This allows for compositional diagrams with fields of units of different dimensionality or different connectedness values of polyhedra. For hydrated oxysalts, it is shown that incorporation of water and acid also reduces dimensionality.

Keywords:   ionic component, structure-composition correlation, compositional diagrams, dimensionality, hydrated oxysalts, water

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