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Advanced Structural Inorganic Chemistry$
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Wai-Kee Li, Gong-Du Zhou, and Thomas Mak

Print publication date: 2008

Print ISBN-13: 9780199216949

Published to Oxford Scholarship Online: May 2008

DOI: 10.1093/acprof:oso/9780199216949.001.0001

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Structural Chemistry of Hydrogen

Structural Chemistry of Hydrogen

Chapter:
(p.399) 11 Structural Chemistry of Hydrogen
Source:
Advanced Structural Inorganic Chemistry
Author(s):

Wai-Kee Li

Gong-Du Zhou

Thomas Chung Wai Mak

Publisher:
Oxford University Press
DOI:10.1093/acprof:oso/9780199216949.003.0011

Even though hydrogen is the ‘simplest’ atom in the Periodic Table, it has a very rich structural chemistry with eight bonding types. This chapter discusses the nature of the hydrogen bond, non-conventional hydrogen bonds (X-H···π, X-H···M, X-H···H-E, etc.), hydride complexes, molecular hydrogen coordination compounds, and σ-bond complexes.

Keywords:   agnostic bond, dihydrogen bond, hydride complex, hydrogen bonding, hydrogen bridging bond, isotopes of hydrogen, molecular hydrogen coordination compounds, polymeric hydrogen, σ-bond complexes

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