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The Nature of the Hydrogen BondOutline of a Comprehensive Hydrogen Bond Theory$
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Gastone Gilli and Paola Gilli

Print publication date: 2009

Print ISBN-13: 9780199558964

Published to Oxford Scholarship Online: September 2009

DOI: 10.1093/acprof:oso/9780199558964.001.0001

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PRINTED FROM OXFORD SCHOLARSHIP ONLINE (oxford.universitypressscholarship.com). (c) Copyright Oxford University Press, 2021. All Rights Reserved. An individual user may print out a PDF of a single chapter of a monograph in OSO for personal use. date: 23 January 2022

INTRODUCTION

INTRODUCTION

Chapter:
(p.1) INTRODUCTION
Source:
The Nature of the Hydrogen Bond
Author(s):

Gastone Gilli

Paola Gilli

Publisher:
Oxford University Press
DOI:10.1093/acprof:oso/9780199558964.003.0001

This chapter represents a short introduction to the main themes developed in the book. It starts from the consideration that the H-bond, though discovered more than eighty years ago and universally recognized of crucial importance in chemistry and biology, is still lacking a theoretical interpretation general enough to account for its most salient features. The method used for solving this problem (here called the H-bond puzzle) is outlined as an essentially empirical case-study strategy which makes provisional tabula rasa of all previous theories and, taking advantage of the great experimental and computational advances occurred in the last few decades, trys to infer internally coherent and consistent conclusions on the very nature of the H-bond from the ensemble of the data collected. The chapter also includes a useful summary of the contents of the other chapters of the book.

Keywords:   H-bond puzzle, methodology, theoretical interpretation, salient features

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