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Electronic and Optical Properties of Conjugated Polymers$
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William Barford

Print publication date: 2013

Print ISBN-13: 9780199677467

Published to Oxford Scholarship Online: May 2013

DOI: 10.1093/acprof:oso/9780199677467.001.0001

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Optical processes in conjugated polymers

Optical processes in conjugated polymers

Chapter:
(p.192) 11 Optical processes in conjugated polymers
Source:
Electronic and Optical Properties of Conjugated Polymers
Author(s):

William Barford

Publisher:
Oxford University Press
DOI:10.1093/acprof:oso/9780199677467.003.0011

The theory of linear and non-linear optical processes in conjugated polymers is introduced. In particular, the Condon approximation, Franck-Condon factors, and exciton model are all used to develop expressions for transition dipole moments between the electronic states. The non-linear processes of two-photon absorption and electroabsorption are discussed within the context of the essentials states mechanism.The chapter concludes with a discussion of photo-physical processes via a Jablonski diagram.

Keywords:   linear optical processes, Condon approximation, Franck-Condon factors, transition dipole moments, two-photon absorption, electroabsorption, essentials states mechanism, Jablonski diagram

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