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The Chemistry of WineFrom Blossom to Beverage and Beyond$
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David R. Dalton

Print publication date: 2018

Print ISBN-13: 9780190687199

Published to Oxford Scholarship Online: November 2020

DOI: 10.1093/oso/9780190687199.001.0001

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PRINTED FROM OXFORD SCHOLARSHIP ONLINE (oxford.universitypressscholarship.com). (c) Copyright Oxford University Press, 2021. All Rights Reserved. An individual user may print out a PDF of a single chapter of a monograph in OSO for personal use. date: 22 October 2021

Finishing the Wine

Finishing the Wine

19 (p.231) Finishing the Wine
The Chemistry of Wine

David R. Dalton

Oxford University Press

The end of fermentation, signaled by density measurements, the alcohol-driven death of the Saccharomyces cerevisiae strain that was used, the cessation of evolution of carbon dioxide, and the generally accepted passage of the several weeks over which time the fermentation has been permitted to extend, is followed by the previously discussed (Chapter 16) process of racking. The racking, as noted earlier, will separate most of the precipitated solids that are present or have developed during the fermentation process (e.g., accumulated seed and twig pieces not previously removed, insoluble carboxylic acid salts, dead yeast cells, and other solids [the lees]) from the fermented juice. But the wine may not yet be clear. Indeed, the wine may need racking once or twice more for clarification before a final filtration to produce the appropriate bright and clear beverage-quality wine. The last, or even a penultimate racking, might be done into an oaken vessel and should be done into oak if a red wine is being finished (European or American oaks are commonly used, but with different results, vide infra). However, it is important that regardless of the color of the wine each racking operation be done as carefully as possible to exclude transfer of solids and oxygen. At this stage of finishing, the oxygen will probably not be utilized in biochemical processes, barring the presence of microbial life, and normal oxidation of phenols and alcohols in the wine will have been inhibited by the presence of carbon dioxide (which replaced the oxygen in the solution during fermentation). Thus, if oxygen is introduced, it is likely that unwanted oxidation products might form. The final racking for white wines (excluding Champagne, other “sparkling” wines, and some specialty beverages to be considered later) is generally carried out so that the beverage can rest for a few months (often with cooling to inhibit deleterious processes occurring as a result of aging) before filtering and bottling.

Keywords:   acetaldehyde, bentonite, castalagin, enol, furfural, globulin, hydroxyimine, procyanidins, vanillic acid, vitamin C

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